NUS chemists have developed a new "catalyst control" blueprint to overcome a longstanding challenge in the site-selective dicarbofunctionalization of unactivated alkenes, by enabling the reaction to ...
Chemists at the Max-Planck-Institut für Kohlenforschung have developed a practical two-step method for alkylating alkenes via thianthrenation, addressing a long-standing synthetic challenge. This ...
Chemists have developed a straightforward method to convert common chemicals like carboxylic acids, alcohols, and alkanes directly into valuable alkenes. Chemists from the National University of ...
Two different nitroalkane molecules are activated by visible light and knit together to form a complex alkene in a new reaction reported independently by two groups. Credit: Adapted from J. Am. Chem.
A dilute solution of bromine is added to samples of heptane and cyclohexene. The bromination reactions and mechanisms are compared. UV light splits the bromine molecule into two reactive radicals, ...
Cyclopropanes are a common motif in medicinal chemistry. Three-carbon rings show up in drug structures for conditions including asthma, psoriasis, and COVID-19. But despite its utility, cyclopropane ...